This list contains the desk accessories that will be initially opened by MultiFinder. This list is only active if MultiFinder is the selected system. This list has no affect on the desk accessories that will be available after the system has started.
If you are a Suitcase or MasterJuggler user, you will notice that only the desk accessories actually in the system folder will be listed. This is a limitation of the current version of FreshStart which may be removed in a future version.